Inside Angelina Jolie’s tangled love life after her shock divorce from Brad Pitt

AS NEWS of Angelina Jolie’s split from Brad Pitt unfolds, we take a look back at the Hollywood star’s salacious love life.

AS NEWS of Angelina Jolie’s split from Brad Pitt hits the headlines, we take a look back at the Hollywood star’s tangled love life.

From wearing a vial of her ex’s blood to dating women, and being accused of breaking up marriages, the 41-year-old is no stranger to scandal when it comes to relationships.

SHOCK SPLIT: Angelina Jolie files for divorce from Brad Pitt

Angelina Jolie' and Brad Pitt have called it quits. Picture: Kevin Winter/Getty Images

The Sun reports Jolie had her first serious boyfriend when she was just 14.

Her mother even allowed them to live together in her home, with the actress revealing: “I was either going to be reckless on the streets with my boyfriend or he was going to be with me in my bedroom with my mom in the next room.

“She made the choice, and because of it, I continued to go to school every morning and explored my first relationship in a safe way.”

She later compared this teen relationship to a marriage because it was so intense — and claimed the breakup compelled her to start acting when she was 16.

Angelina Jolie is no stranger to scandal when it comes to relationships. Picture: Ethan Miller/Getty Images

Jonny Lee Miller (1995 — 1999)

The pair became romantically involved during the filming of Hackers in 1995. Miller is reported to have been Jolie’s first lover since her teenage relationship.

After production on the film ended, the duo didn’t stay in touch for many months after, but eventually reconnected and married on March 28, 1996.

Controversial as ever, Jolie married Miller while wearing black rubber trousers and a white T-shirt — which had the groom’s name written in her blood across it. Apparently she believed doing this would seal their marriage and mean that he would never leave her.

The pair separated in September 1997 and divorced on February 3, 1999.

Angelina Jolie and Jonny Lee Miller in a scene from 1995 film Hackers. Picture: Supplied

Jenny Shimizu (1996)

Jolie began a relationship with model-actress Jenny Shimizu on the set of 1996 film Foxfire.

She said of the relationship: “I would probably have married Jenny if I hadn’t married my husband. I fell in love with her the first second I saw her.”

Angelina Jolie dated model-actress Jenny Shimizu. Picture: Supplied

Billy Bob Thornton (1999 — 2003)

Jolie married actor Billy Bob Thornton on May 5, 2000, in Las Vegas, following a two-month romance.

The couple met on the set of 1999 film Pushing Tin but didn’t pursue a relationship as Thornton was engaged to actress Laura Dern, while Jolie was reportedly dating actor Timothy Hutton.

The pair made an array of weird and wonderful public declarations of passion, most famously wearing one another’s blood in vials around their necks.

The pair announced their separation in 2002 — just three months after announcing that they would be adopting a child from Cambodia together.

Angelina Jolie wed Billy Bob Thornton after a whirlwind romance. Picture: Supplied

Brad Pitt (2004 — 2016)

This was Jolie’s most controversial relationship. Jolie and Brad Pitt allegedly started their romance on the set of 2005 film Mr & Mrs Smith — but both deny this was the case.

The relationship became a Hollywood scandal and was cited as the main reason for Pitt’s divorce from Friends star Jennifer Aniston.

While Jolie did deny the pair had an affair on set, she is also quoted as saying that they “fell in love” while making the film.

She added: “To be intimate with a married man, when my own father cheated on my mother, is not something I could forgive.

“I could not look at myself in the morning if I did that. I wouldn’t be attracted to a man who would cheat on his wife.”

In January 2006, Angelina confirmed that she was pregnant with Pitt’s child and the couple went on to announce their engagement in April 2012. The pair married on August 23, 2014, at their French estate.

Angelina Jolie and Brad Pitt have three adopted and three biological children together. Picture: Pascal Le Segretain/Getty Images

However, the Hollywood actress has now filed for divorce citing irreconcilable differences and wants overall physical custody of their six children — not joint custody with Brad.

The couple have six kids together — Maddox, 15, Zahara, 11, Shiloh, 10, Pax, 12 and eight-year-old twins, Knox and Vivienne.

Jolie has also been romantically linked to Val Kilmer, Colin Farrell and Gia co-star Elizabeth Mitchell.

Angelina Jolie reportedly once dated actor Val Kilmer. Picture: Supplied

Angelina Jolie is rumoured to have dated Colin Farrell. Picture: Larry Busacca/Getty Images

This story originally appeared in The Sun.